If you are using a DSLR, then you can't just set the shutter to BULB mode and leave it open for much longer than 4 - 5 minutes, as this will introduce way too much noise into the resulting image.
The best technique that I have found is actually outlined by Moose Peterson in this article on his website:
http://www.moosepeterson.com/digital...he_Heavens.pdf
I know of a few other photogs who have tried this technique with awesome results, though I have not yet had a chance to try it out myself.
Hope this helps!